| 13/09/2020 | Real Valladolid vs Real Sociedad | 1 - 1 | 95 | 0 |
| 20/09/2020 | Real Betis vs Real Valladolid | 2 - 0 | 95 | -1 |
| 27/09/2020 | Real Valladolid vs Celta Vigo | 1 - 1 | 95 | -1 |
| 30/09/2020 | Real Madrid vs Real Valladolid | 1 - 0 | 94 | -1 |
| 18/10/2020 | Huesca vs Real Valladolid | 2 - 2 | 93 | 2 |
| 02/11/2020 | Villarreal vs Real Valladolid | 2 - 0 | 94 | -1 |
| 08/11/2020 | Real Valladolid vs Athletic Bilbao | 2 - 1 | 96 | 0 |
| 22/11/2020 | Granada vs Real Valladolid | 1 - 3 | 95 | 0 |
| 27/11/2020 | Real Valladolid vs Levante | 1 - 1 | 94 | 0 |
| 05/12/2020 | Atletico Madrid vs Real Valladolid | 2 - 0 | 94 | -1 |
| 11/12/2020 | Real Valladolid vs Osasuna | 3 - 2 | 96 | -1 |
| 19/12/2020 | Sevilla vs Real Valladolid | 1 - 1 | 96 | -1 |
| 29/12/2020 | Cádiz vs Real Valladolid | 0 - 0 | 93 | 5 |
| 02/01/2021 | Getafe vs Real Valladolid | 0 - 1 | 96 | 5 |
| 10/01/2021 | Real Valladolid vs Valencia | 0 - 1 | 97 | -1 |
| 22/01/2021 | Levante vs Real Valladolid | 2 - 2 | 93 | -1 |
| 29/01/2021 | Real Valladolid vs Huesca | 1 - 3 | 94 | -2 |
| 05/02/2021 | Alaves vs Real Valladolid | 1 - 0 | 95 | -1 |
| 13/02/2021 | Eibar vs Real Valladolid | 1 - 1 | 94 | 0 |
| 20/02/2021 | Real Valladolid vs Real Madrid | 0 - 1 | 94 | 0 |
| 28/02/2021 | Celta Vigo vs Real Valladolid | 1 - 1 | 96 | 0 |
| 13/03/2021 | Osasuna vs Real Valladolid | 0 - 0 | 11 | 5 |
| 20/03/2021 | Real Valladolid vs Sevilla | 1 - 1 | 11 | 0 |
| 05/04/2021 | Barcelona vs Real Valladolid | 1 - 0 | 94 | -1 |
| 11/04/2021 | Real Valladolid vs Granada | 1 - 2 | 96 | -2 |
| 21/04/2021 | Elche vs Real Valladolid | 1 - 1 | 95 | 0 |
| 13/05/2021 | Real Valladolid vs Villarreal | 0 - 2 | 94 | -1 |
